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Figure 1:
a,b) Recorded spectrum with the investigated
spectral lines of 3s-3p
a) Exp. B2 (T = 35 000 K , ![]() ![]() |
Plasma reproducibility was monitored by the N III line radiation and,
also, by the discharge current (it was found to be within 6%). The measured
profiles were of the Voigt type due to the convolution of the Lorentzian
Stark and Gaussian profiles caused by Doppler and instrumental broadening.
For electron density and temperature obtained in our experiment the Lorentzian
fraction in the Voigt profile was dominant. Van der Waals and resonance
broadening were estimated to be smaller by more than an order of magnitude in
comparison to Stark, Doppler and instrumental broadening. A standard
deconvolution procedure (Davies & Vaughan 1963) was used. The
deconvolution procedure was computerized using the least square algorithm. The
Stark widths
were measured with 12% error. Great care was taken to minimize the
influence of self-absorption on Stark width determinations. The opacity was
checked by measuring relative line intensity ratios within multiplet No. 1
and No. 2. The values obtained were compared with calculated ratios of the
products of the spontaneous emission probabilities and the corresponding
statistical weights of the upper levels of the lines. The necessary atomic
data were taken from Glenzer et al. (1994b).
It turns out that these
ratios differed by less than
8% which testifies the absence of
self-absorption. The Stark shifts were measured relative to the unshifted
spectral lines emitted by the same plasma using the method described by
Puric & Konjevic (1972). Stark shift data are determined with
0.0015 nm errors at a given N and T. The plasma
parameters were determined using standard diagnostics
methods (Rompe & Steenbeck 1967). The electron temperature was determined from the
ratios of the
relative intensities of the 348.49 nm N IV to 393.85 nm N III and the
previous N III to 399.50 nm N II spectral lines, assuming the
existence of LTE, with an estimated error of
10% (experiment A) and
from the ratios of the relative intensities of the investigated four
N III spectral lines to 463.05 nm and 464.31 nm N II spectral lines
with an
estimated error of
9% (experiment B). In the experiment B the electron
temperature was, also, determined from the ratio of the relative intensities of
the He II P
(468.6 nm) to 587.6 nm He I spectral lines.
All the necessary atomic parameters were taken from
Glenzer et al. (1994b) and Wiese et al. (1966).
The electron density (N) decay
was measured using a well known single wavelength He-Ne laser interferometer for
the 632.8 nm transition with an estimated error of
7%.
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