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1. Introduction

Atomic quantities such as oscillator strengths, spectral line wavelengths, energy levels and ionization potentials depend on the nuclear charge number Z. Methods of plotting such atomic data along isoelectronic sequences have been in use for a long time. For example, this was how Edlén (1942) showed that the mysterious green coronal line originates from a forbidden transition within the ground configuration of Fe XIV. He had the simple but astute idea of plotting essentially the fourth root of the ground term splitting tex2html_wrap_inline1093 as a function of Z. The resulting reduced splittings deduced from laboratory spectra of neutral aluminium and the first eight ions of the sequence lie on a smooth curve. When extended to higher values of Z the curve is seen to coincide with the coronal lines tex2html_wrap_inline1099 and tex2html_wrap_inline1101, assuming they come from Fe XIV and Ni XVI respectively.

Here we show how the program OMEUPS developed by Burgess (see Burgess & Tully 1992) can be used for exhibiting and spline fitting atomic data along an isoelectronic sequence. Instead of inputting the collision strength tex2html_wrap_inline1103 as a function of the final collision energy E, we input A(Z) where A is the quantity under study and Z is the atomic, or nuclear charge, number. An attractive feature of OMEUPS is that it makes use of interactive graphics. The program transforms A(Z) to a reduced form tex2html_wrap_inline1115 where the reduced charge number tex2html_wrap_inline1117 varies from zero when tex2html_wrap_inline1119 to unity when tex2html_wrap_inline1121. The value assigned to tex2html_wrap_inline1123 determines the range of elements we wish to include. In general we assume tex2html_wrap_inline1125, where N is the number of bound electrons, so that the range includes the neutral atom and all positive ions. A parameter C occurs in the definition of tex2html_wrap_inline1131 to provide a useful degree of flexibility for modifying the plot. By varying the value of C one alters the way in which the data points are distributed across the figure. In many cases tex2html_wrap_inline1135 tends to a finite limit at tex2html_wrap_inline1137 which can be determined. This is often helpful when approximating the data points by a least squares 5 point cubic spline. The program carries out the spline fitting procedure efficiently and rapidly.

We compare our method with Edlén's for a fine structure transition in the aluminium sequence (see Fig. 3 (click here)) and give other examples to show the usefulness and versatility of the present approach.

  figure213
Figure 1: Fluorine sequence: tex2html_wrap_inline1139, tex2html_wrap_inline1141, C = 4.4

Preliminary versions of the examples given here were presented at the 5th International Colloquium on Atomic Spectra and Oscillator Strengths for Astrophysical and Laboratory Plasmas which was held at the Observatoire de Paris (Meudon) from 28 to 31 August 1995.


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