For electron impact with ions, the collision strength is finite at threshold
and in the high energy asymptotic limit it displays logarithmic, constant or
inverse square behaviour depending on whether the transition is of dipole,
non-dipole, non-spin change or spin change type. There are also intermediate
cases of small oscillator strength. It was pointed out by Burgess & Tully
(1992)
that, with the emphasis on large collision calculations, such as those using the R-matrix method,
and with the focus on resonance structure, attention was often not given to ensuring
the correct continuation of the collision strength from low energies into the
Born and Born/Ochkur regime at high energy. While this did not matter for
forbidden line formation in nebulae, it certainly did for fusion plasma
applications. In the latter case, inflowing impurity species can find themselves
in temperature regimes spanning from well below the ionisation energy to far
above it. The high energy behaviour is of course simply prescribed, given
the atomic structure, in terms of oscillator strength or first Born
coefficients. Properly, the whole energy range of collision strength data should be
provided for applications and the Burgess-Tully method of mapping the energy from threshold
to infinity onto [0, 1] emphasised this. With the finite behaviour at
threshold, the scaled collision strength for ions, as a function of scaled
energy, displayed small variation over the whole independent variable range
such that it could be well represented by a simple five-point equally-spaced
knot spline. A single parameter, C, allowed a scale distortion in the
independent variable by which the spline could be optimised. The plots became
known as "C-plots'' and often showed up embarrassing deficiencies in the
original data.
With the introduction of divertor technology into magnetically confined fusion
plasma design and the resurgence of discharge devices for plasma processing,
neutral atoms and molecules are now very much the focus of interest in the laboratory
environment (Behringer & Fantz 1996) as well as of continuing importance in astrophysics (see, for
example, the recent first observation of the neutral helium intercombination line in the solar
atmosphere by Brooks et al. 1999).
Collision strengths for neutrals are zero at threshold, with the behaviour near
threshold dependent on the dominant partial wave in the N+1 electron system.
Also, collision data is usually presented on scales which conceal the
threshold region. The problem is analogous to that for the high energy region
and a similar opening out of the threshold region as Burgess & Tully did for
the high energy region is desirable. There is a second issue. The
Burgess-Tully method is not a faithful representation of the original data but
a considered (and hopefully) improved conversion of the data. A second path
of fitting data is that of strict interpolation on the assumption that the
source data is exact. For this it is helpful to prepare an analytic
approximate form
which can be compared with the tabulated
collision strength
.
It is useful if optimised fitting and interpolative
fitting run side by side. Within the Atomic Data and Analysis Structure (ADAS) Project,
established in support of the SOHO spacecraft and solar astrophysics (Mason et al. 1997;
Summers et al. 1998; Summers 1993, 1999), both methods are used
with the latter designed also to highlight misprints and errors of data entry.
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