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Astronomy and Astrophysics Supplement Series, Vol. 117, June I 1996, 377-392
Computed distributions of rotovibrational transitions in
LiH (
)
and LiH
(
)
F.A. Gianturco
Send offprint requests to: F.A. Gianturco
, P. Gori Giorgi
, H.
Berriche
and F.X. Gadea
Department of Chemistry, The University of Rome,
Cittá Universitaria, 00185 Rome, Italy
Laboratoire de Physique Quantique, Université Paul Sabatier, 118
Rue de Narbonne, 31062 Toulouse Cedex, France
Received October 6; accepted November 21, 1995
Abstract:
Accurate potential energy curves for the ground electronic states of LiH and
are employed to generate
vibrational and rotational levels over a broad range of J
values for both systems. The corresponding dipole functions are
computed and used to obtain the frequency and intensity
distributions of all relevant transitions between bound states
for pure vibrational excitations, pure rotational excitations
and for dipole allowed rovibrational processes. This
extensive set of absorption data for both molecules is employed
to locate the most likely region in the infrared spectrum where
characteristic lines could be observed. Such data should be
useful in experimental attempts to search for LiH and
lines at high redshifts. We found that transitions
between ionic levels will be markedly less intense than those
for the neutral system and that transitions between rotationally
`hot' levels will be markedly more intense than those between
low-J levels.
Key words: molecular data --- cosmology: miscellaneous
web@edpsciences.com
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